The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide

Gulaim Seisenbaeva; Suresh Gohil; Vadim Kessler; Tatiana V. Rogova; Evgeniya V. Suslova; Nataliya Ya. Turova

doi:10.1016/j.ica.2005.03.048

The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide

Gulaim Seisenbaeva
, Suresh Gohil
, Vadim Kessler
, Tatiana V. Rogova
, Evgeniya V. Suslova
, Nataliya Ya. Turova

Publikation: Bidrag till tidskrift › Artikel i vetenskaplig tidskrift › Peer review

Sammanfattning

interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)(13), and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)(12)X and Fe5O(OEt)(11)X-2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)(13) isolated with higher yields. (c) 2005 Elsevier B.V. All rights reserved.

Originalspråk	Engelska
Sidor (från-till)	3506-3512
Antal sidor	7
Tidskrift	Inorganica Chimica Acta
Volym	358
Nummer	12
DOI	https://doi.org/10.1016/j.ica.2005.03.048
Status	Publicerad - 2005

Nyckelord

iron oxo-ethoxide
mass-spectrometry
X-ray study
sol-gel

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10.1016/j.ica.2005.03.048

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title = "The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide",

abstract = "interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)(13), and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)(12)X and Fe5O(OEt)(11)X-2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)(13) isolated with higher yields. (c) 2005 Elsevier B.V. All rights reserved.",

keywords = "iron oxo-ethoxide, mass-spectrometry, X-ray study, sol-gel, iron oxo-ethoxide, mass-spectrometry, X-ray study, sol-gel",

author = "Gulaim Seisenbaeva and Suresh Gohil and Vadim Kessler and Rogova, \{Tatiana V.\} and Suslova, \{Evgeniya V.\} and Turova, \{Nataliya Ya.\}",

year = "2005",

doi = "10.1016/j.ica.2005.03.048",

language = "English",

volume = "358",

pages = "3506--3512",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

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}

TY - JOUR

T1 - The synthesis of iron (III) ethoxide revisited: Characterization of the metathesis products of iron (III) halides and sodium ethoxide

AU - Seisenbaeva, Gulaim

AU - Gohil, Suresh

AU - Kessler, Vadim

AU - Rogova, Tatiana V.

AU - Suslova, Evgeniya V.

AU - Turova, Nataliya Ya.

PY - 2005

Y1 - 2005

N2 - interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)(13), and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)(12)X and Fe5O(OEt)(11)X-2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)(13) isolated with higher yields. (c) 2005 Elsevier B.V. All rights reserved.

AB - interaction of FeX3, X = Cl, Br with 3 equiv. of NaOEt in toluene/ethanol media provides mixtures of iron (III) oxoethoxide, Fe5O(OEt)(13), and its halide alkoxide analogs. The latter have been identified by mass-spectrometric study as Fe5O(OEt)(12)X and Fe5O(OEt)(11)X-2. Application of FeBr3 as a starting material leads to much more pure samples of Fe5O(OEt)(13) isolated with higher yields. (c) 2005 Elsevier B.V. All rights reserved.

KW - iron oxo-ethoxide

KW - mass-spectrometry

KW - X-ray study

KW - sol-gel

KW - iron oxo-ethoxide

KW - mass-spectrometry

KW - X-ray study

KW - sol-gel

UR - https://res.slu.se/id/publ/7993

U2 - 10.1016/j.ica.2005.03.048

DO - 10.1016/j.ica.2005.03.048

M3 - Journal article

SN - 0020-1693

VL - 358

SP - 3506

EP - 3512

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 12

ER -