Synthesis and structure of dioxomolybdenum(VI) complex of amine triphenolato ligand

Vadim Kessler; A Lehtonen

doi:10.1016/j.inoche.2004.03.020

Synthesis and structure of dioxomolybdenum(VI) complex of amine triphenolato ligand

Vadim Kessler
, A Lehtonen

Publication: Contribution to journal › Journal article › peer-review

Abstract

Addition of two equivalents of tris(2-hydroxy-3,5-dimethylbenzyl)amine (H(3)Lig) to the solution of MoO2(acac)(2) in MeOH results in the formation of anionic complex, which precipitates as LigH(4)[MoO(2)Lig], a yellow crystalline solid. Crystal structure determinations reveal that the asymmetric unit consists of one [MoO(2)Lig](-) anion, one H(4)Lig(+) cation and two molecules of solvent. Three phenoxide groups of the tetradentate ligand are bonded to cis-MoO22+ -ion in xy-plane, while the amino nitrogen atom completes the distorted octahedral coordination. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	691-693
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	5
DOIs	https://doi.org/10.1016/j.inoche.2004.03.020
Publication status	Published - 2004

Keywords

molybdenum complex
phenoxide complex
crystal structure
atranes

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10.1016/j.inoche.2004.03.020

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@article{f62727b5da2d4f91a7f391a3e401c045,

title = "Synthesis and structure of dioxomolybdenum(VI) complex of amine triphenolato ligand",

abstract = "Addition of two equivalents of tris(2-hydroxy-3,5-dimethylbenzyl)amine (H(3)Lig) to the solution of MoO2(acac)(2) in MeOH results in the formation of anionic complex, which precipitates as LigH(4)[MoO(2)Lig], a yellow crystalline solid. Crystal structure determinations reveal that the asymmetric unit consists of one [MoO(2)Lig](-) anion, one H(4)Lig(+) cation and two molecules of solvent. Three phenoxide groups of the tetradentate ligand are bonded to cis-MoO22+ -ion in xy-plane, while the amino nitrogen atom completes the distorted octahedral coordination. (C) 2004 Elsevier B.V. All rights reserved.",

keywords = "molybdenum complex, phenoxide complex, crystal structure, atranes, molybdenum complex, phenoxide complex, crystal structure, atranes",

author = "Vadim Kessler and A Lehtonen",

year = "2004",

doi = "10.1016/j.inoche.2004.03.020",

language = "English",

volume = "7",

pages = "691--693",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "5",

}

TY - JOUR

T1 - Synthesis and structure of dioxomolybdenum(VI) complex of amine triphenolato ligand

AU - Kessler, Vadim

AU - Lehtonen, A

PY - 2004

Y1 - 2004

N2 - Addition of two equivalents of tris(2-hydroxy-3,5-dimethylbenzyl)amine (H(3)Lig) to the solution of MoO2(acac)(2) in MeOH results in the formation of anionic complex, which precipitates as LigH(4)[MoO(2)Lig], a yellow crystalline solid. Crystal structure determinations reveal that the asymmetric unit consists of one [MoO(2)Lig](-) anion, one H(4)Lig(+) cation and two molecules of solvent. Three phenoxide groups of the tetradentate ligand are bonded to cis-MoO22+ -ion in xy-plane, while the amino nitrogen atom completes the distorted octahedral coordination. (C) 2004 Elsevier B.V. All rights reserved.

AB - Addition of two equivalents of tris(2-hydroxy-3,5-dimethylbenzyl)amine (H(3)Lig) to the solution of MoO2(acac)(2) in MeOH results in the formation of anionic complex, which precipitates as LigH(4)[MoO(2)Lig], a yellow crystalline solid. Crystal structure determinations reveal that the asymmetric unit consists of one [MoO(2)Lig](-) anion, one H(4)Lig(+) cation and two molecules of solvent. Three phenoxide groups of the tetradentate ligand are bonded to cis-MoO22+ -ion in xy-plane, while the amino nitrogen atom completes the distorted octahedral coordination. (C) 2004 Elsevier B.V. All rights reserved.

KW - molybdenum complex

KW - phenoxide complex

KW - crystal structure

KW - atranes

KW - molybdenum complex

KW - phenoxide complex

KW - crystal structure

KW - atranes

UR - https://res.slu.se/id/publ/2909

U2 - 10.1016/j.inoche.2004.03.020

DO - 10.1016/j.inoche.2004.03.020

M3 - Journal article

SN - 1387-7003

VL - 7

SP - 691

EP - 693

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 5

ER -

Synthesis and structure of dioxomolybdenum(VI) complex of amine triphenolato ligand

Abstract

Keywords

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