Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

Vadim Kessler; H J M Bouwmeester; D H A Blank; G I Spijksma

doi:10.1016/j.inoche.2004.06.006

Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

Vadim Kessler
, H J M Bouwmeester
, D H A Blank
, G I Spijksma

Publication: Contribution to journal › Journal article › peer-review

Abstract

New heterometallic interesting trinuclear, Zr{eta(3), mu(2)-NH(c(2)H(4)O(2)}(3)[Ti((OPr)-Pr-i)(3)](2) encountering a nona-coordinated central zirconium atom crystallizes at -30 degreesC from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L = 1:23) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol-gel technique for the preparation of mixed metal oxide materials. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	953-955
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	8
DOIs	https://doi.org/10.1016/j.inoche.2004.06.006
Publication status	Published - 2004

Keywords

heterometallic alkoxides
X-ray structure
nona-coordinated zirconium

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10.1016/j.inoche.2004.06.006

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title = "Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics",

abstract = "New heterometallic interesting trinuclear, Zr\{eta(3), mu(2)-NH(c(2)H(4)O(2)\}(3)[Ti((OPr)-Pr-i)(3)](2) encountering a nona-coordinated central zirconium atom crystallizes at -30 degreesC from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L = 1:23) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol-gel technique for the preparation of mixed metal oxide materials. (C) 2004 Elsevier B.V. All rights reserved.",

keywords = "heterometallic alkoxides, X-ray structure, nona-coordinated zirconium, heterometallic alkoxides, X-ray structure, nona-coordinated zirconium",

author = "Vadim Kessler and Bouwmeester, \{H J M\} and Blank, \{D H A\} and Spijksma, \{G I\}",

year = "2004",

doi = "10.1016/j.inoche.2004.06.006",

language = "English",

volume = "7",

pages = "953--955",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "8",

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TY - JOUR

T1 - Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

AU - Kessler, Vadim

AU - Bouwmeester, H J M

AU - Blank, D H A

AU - Spijksma, G I

PY - 2004

Y1 - 2004

N2 - New heterometallic interesting trinuclear, Zr{eta(3), mu(2)-NH(c(2)H(4)O(2)}(3)[Ti((OPr)-Pr-i)(3)](2) encountering a nona-coordinated central zirconium atom crystallizes at -30 degreesC from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L = 1:23) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol-gel technique for the preparation of mixed metal oxide materials. (C) 2004 Elsevier B.V. All rights reserved.

AB - New heterometallic interesting trinuclear, Zr{eta(3), mu(2)-NH(c(2)H(4)O(2)}(3)[Ti((OPr)-Pr-i)(3)](2) encountering a nona-coordinated central zirconium atom crystallizes at -30 degreesC from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L = 1:23) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol-gel technique for the preparation of mixed metal oxide materials. (C) 2004 Elsevier B.V. All rights reserved.

KW - heterometallic alkoxides

KW - X-ray structure

KW - nona-coordinated zirconium

KW - heterometallic alkoxides

KW - X-ray structure

KW - nona-coordinated zirconium

UR - https://res.slu.se/id/publ/2920

U2 - 10.1016/j.inoche.2004.06.006

DO - 10.1016/j.inoche.2004.06.006

M3 - Journal article

SN - 1387-7003

VL - 7

SP - 953

EP - 955

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

Abstract

Keywords

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