Electrosynthesis of tin(II) alkoxides

Vadim Kessler; Alexandr I. Belokon'; Evgeniya V. Suslova; Nataliya Ya. Turova

doi:10.1134/S0036023607110083

Electrosynthesis of tin(II) alkoxides

Vadim Kessler
, Alexandr I. Belokon'
, Evgeniya V. Suslova
, Nataliya Ya. Turova

Publication: Contribution to journal › Journal article › peer-review

Abstract

The anodic dissolution of tin metal in absolute alcohols yields oxoalkoxides with the general formula Sn6O4(OR)(4) (R = Me (1), Et (2), i-Pr (3)) and orthoalkoxides with the general formula Sn(OR)(2) (R = n-Bu (4), C2H4OMe (5)). According to X-ray crystallographic data, the molecule of Sn6O4(OEt)(4) (2) is an octahedral [Sn-6] cluster with alternating oxo and OEt groups on its faces. The mass spectra of 1 and 2 indicate the presence of fragments of the hexanuclear oxoalkoxides.

Original language	English
Pages (from-to)	1682-1686
Number of pages	5
Journal	Russian Journal of Inorganic Chemistry / Zhurnal Neorganicheskoi Khimii
Volume	52
Issue number	11
DOIs	https://doi.org/10.1134/S0036023607110083
Publication status	Published - 2007

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title = "Electrosynthesis of tin(II) alkoxides",

abstract = "The anodic dissolution of tin metal in absolute alcohols yields oxoalkoxides with the general formula Sn6O4(OR)(4) (R = Me (1), Et (2), i-Pr (3)) and orthoalkoxides with the general formula Sn(OR)(2) (R = n-Bu (4), C2H4OMe (5)). According to X-ray crystallographic data, the molecule of Sn6O4(OEt)(4) (2) is an octahedral [Sn-6] cluster with alternating oxo and OEt groups on its faces. The mass spectra of 1 and 2 indicate the presence of fragments of the hexanuclear oxoalkoxides.",

author = "Vadim Kessler and Belokon', \{Alexandr I.\} and Suslova, \{Evgeniya V.\} and Turova, \{Nataliya Ya.\}",

year = "2007",

doi = "10.1134/S0036023607110083",

language = "English",

volume = "52",

pages = "1682--1686",

journal = "Russian Journal of Inorganic Chemistry / Zhurnal Neorganicheskoi Khimii",

issn = "0036-0236",

publisher = "Maik Nauka/Interperiodica/Springer",

number = "11",

}

TY - JOUR

T1 - Electrosynthesis of tin(II) alkoxides

AU - Kessler, Vadim

AU - Belokon', Alexandr I.

AU - Suslova, Evgeniya V.

AU - Turova, Nataliya Ya.

PY - 2007

Y1 - 2007

N2 - The anodic dissolution of tin metal in absolute alcohols yields oxoalkoxides with the general formula Sn6O4(OR)(4) (R = Me (1), Et (2), i-Pr (3)) and orthoalkoxides with the general formula Sn(OR)(2) (R = n-Bu (4), C2H4OMe (5)). According to X-ray crystallographic data, the molecule of Sn6O4(OEt)(4) (2) is an octahedral [Sn-6] cluster with alternating oxo and OEt groups on its faces. The mass spectra of 1 and 2 indicate the presence of fragments of the hexanuclear oxoalkoxides.

AB - The anodic dissolution of tin metal in absolute alcohols yields oxoalkoxides with the general formula Sn6O4(OR)(4) (R = Me (1), Et (2), i-Pr (3)) and orthoalkoxides with the general formula Sn(OR)(2) (R = n-Bu (4), C2H4OMe (5)). According to X-ray crystallographic data, the molecule of Sn6O4(OEt)(4) (2) is an octahedral [Sn-6] cluster with alternating oxo and OEt groups on its faces. The mass spectra of 1 and 2 indicate the presence of fragments of the hexanuclear oxoalkoxides.

UR - https://res.slu.se/id/publ/15619

U2 - 10.1134/S0036023607110083

DO - 10.1134/S0036023607110083

M3 - Journal article

SN - 0036-0236

VL - 52

SP - 1682

EP - 1686

JO - Russian Journal of Inorganic Chemistry / Zhurnal Neorganicheskoi Khimii

JF - Russian Journal of Inorganic Chemistry / Zhurnal Neorganicheskoi Khimii

IS - 11

ER -

Electrosynthesis of tin(II) alkoxides

Abstract

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