Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands

Suresh Gohil; Pher G. Andersson; Pradeep Cheruku

doi:10.1021/ol070325l

Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands

Suresh Gohil
, Pher G. Andersson
, Pradeep Cheruku

Publication: Contribution to journal › Journal article › peer-review

Abstract

Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99% ee.

Original language	English
Pages (from-to)	1659-1661
Number of pages	3
Journal	Organic Letters
Volume	9
Issue number	9
DOIs	https://doi.org/10.1021/ol070325l
Publication status	Published - 2007

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title = "Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands",

abstract = "Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99\% ee.",

author = "Suresh Gohil and Andersson, \{Pher G.\} and Pradeep Cheruku",

year = "2007",

doi = "10.1021/ol070325l",

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journal = "Organic Letters",

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T1 - Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands

AU - Gohil, Suresh

AU - Andersson, Pher G.

AU - Cheruku, Pradeep

PY - 2007

Y1 - 2007

N2 - Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99% ee.

AB - Enol phosphinates, which are structural analogues of enol acetates, have for the first time been employed as substrates for Ir-catalyzed asymmetric hydrogenation. A number of enol phosphinates have been synthesized and reduced successfully with up to and above 99% ee.

UR - https://res.slu.se/id/publ/15682

U2 - 10.1021/ol070325l

DO - 10.1021/ol070325l

M3 - Journal article

C2 - 17388604

SN - 1523-7060

VL - 9

SP - 1659

EP - 1661

JO - Organic Letters

JF - Organic Letters

IS - 9

ER -

Asymmetric hydrogenation of enol phosphinates by iridium catalysts having N,P ligands

Abstract

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